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Project Code [2009-PhD-ET-1]

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Project title

Catalysts for the promotion of green selective oxidation reactions

Primary Funding Agency

Environmental Protection Agency

Co-Funding Organisation(s)

n/a

Lead Organisation

University College Dublin (UCD)

Lead Applicant

James Sullivan

Project Abstract

We will synthesise, characterise, apply and optimise supported metallic catalysts containing Pd nanoparticles for H2O2 production (from H2 + O2) and do the same for mesoporous Ti-containing materials to catalyse selective epoxidation of alkenes using H2O2. We will then combine these catalysts to form a material to selectivity epoxidise alkenes using O2(g)/H2(g) as a green oxidant. These processes would have far lower E-factors and higher atom efficiencies than traditional stoichiometric oxidations.The syntheses will involve nanoparticle preparation and deposition and the formation of template-derived mesoporous oxides. Characterisations will include TEM, SEM/EDX, FTIR and Raman spectroscopy, physisiorption and chemisorption measurements.

Grant Approved

�95,000.00

Research Hub

Green and Circular Economy

Research Theme

Waste and Resources Management

Start Date

01/09/2009

Initial Projected Completion Date

01/09/2012